
含氟人工唾液对选择性激光熔积钴铬合金耐腐蚀性的影响
网络出版日期: 2014-04-02
基金资助
上海市科委资助项目(12441903001, 13140902701)
Effects of different fluorine-containing oral artificial saliva solution on anti-corrosion behavior of selective laser melting cobalt-chromium alloy
Online published: 2014-04-02
Supported by
Foundation of Science and Technology Commission of Shanghai Municipality, 12441903001, 13140902701
目的 观察含氟人工唾液对选择性激光熔积技术(SLM)制作的钴铬合金耐腐蚀性的影响。方法 将具有相同成分的钴铬合金粉末和金属块,分别运用SLM技术(SLM组)和铸造工艺(对照组)制作试件,每组40个。分别在pH 为5.0和2.5以及模拟口腔含氟0、0.05%、0.10%和0.20%的条件下,将试件置于Fusayam人工唾液中浸泡24 h。采用极化曲线Tafel外延法求得两组试样的极化阻力Rp值,比较两组试件的耐腐蚀性。结果 pH值为5.0时,在含氟0和0.05%的条件下,两组间Rp值比较差异无统计学意义(P>0.05);而在含氟0.1%和0.2%的条件下,SLM组的Rp值显著大于对照组(P<0.05)。当pH为2.5时,在含氟0、0.05%、0.10%和0.20%的条件下,SLM组的Rp值均显著大于对照组(P<0.05)。结论 氟化物能影响钴铬合金的耐腐蚀性能,SLM钴铬合金的耐腐蚀性优于铸造钴铬合金。
曾 丽 , 张 勇 , 杨 旭 , 等 . 含氟人工唾液对选择性激光熔积钴铬合金耐腐蚀性的影响[J]. 上海交通大学学报(医学版), 2014 , 34(3) : 314 . DOI: 10.3969/j.issn.1674-8115.2014.03.011
Objective To evaluate the effects of different fluoride-containing artificial saliva solution on the corrosion of the dental cobalt-chromium (Co-Cr) alloy fabricated by selective laser melting (SLM). Methods The study involved two groups, each group has 40 cylinder specimens and all specimens were fabricated by the same Co-Cr alloy. One group adopted SLM, while the other group used the cast method. Under conditions of two different pHs (2.5 and 5.0) and four different fluoridecontaining artificial saliva solution concentration (0, 0.05%, 0.1%, and 0.2%), polarization curve tests were performed to compare the anti-corrosion ability of two groups. Results For pH of 5.0 (fluoride-containing artificial saliva solution concentrations were 0 and 0.05%), differences of Rp values between two groups were not statistically significant (P>0.05). For pH of 5.0 (fluoride-containing artificial saliva solution concentration were 0.1% and 0.2%) and pH of 2.5 (fluoride-containing artificial saliva solution concentration were 0, 0.05%, 0.1%, and 0.2%), the Rp value of SLM specimens were significantly higher than those of the cast ones (P<0.05). Conclusion Fluorine can affect the anti-corrosion ability of Co-Cr alloy. SLM specimens exhibited a significantly better anti-corrosion ability than cast ones.
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